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By Buckley O. E.

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G. M. J. Beijersbergen van Henegouwen, J. Photochem. Photobzol. , 1991, 10, 183. 13. K. Thoma and N. Kuebler, Pharmazze, 1996,51,660. 14. J. V. Greenhill in J. Swarbrick and J. C. ), Encyclopedia of Pharmaceutical Technology, Dekker, New York, 1995, Vol. 12, p. 105. 15. T. Oppenlaender, Chimia, 1988,42,331. 16. H. H. Tlannesen and J. Carlsen, Pharmeuropa, 1995,7, 137. 17. H. H. 371. 18. F. Vargas, C. Rivas, M. A. Miranda and F. Bosca, Pharmazze, 1991,46,767. 19. E. Moore and P. P. Chappuis, Photochem.

Castell, M. J. Gomez-Lechon, M. A. Miranda and I. M. Morera, J. Photochem. Photobiol. , 1992, 13, 71. 26. Monti, S. Sortino, G. De Guidi and G. Marconi, J. Chem. , 1997, 93,2269. 27. F. Bosca, M. A. Miranda, G. Carganico and D. Mauleon, Photochem.

I Cardiac Agents. l15 Ubidecarenone (112) has been found to be photolabile in the solid-state. 1 16 (2) 2-amino-5-chlorobenzophenoneamidinohydrazone acetate (1 13), an antiarrhythmically active compound, undergoes geometrical isomerisation and, more slowly, decomposition when exposed to light in aqueous solution. l7 Antianginal and antiarrhythmic amiodarone (1 14) (Scheme 34) was found to deiodinate sequentially upon irradiation in deaerated ethanol to give (1 15) and finally the iodine-free ketone (1 16); in turn, the last compound underwent a-cleavage to give (1 17) when irradiated for a longer time.

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