By Sandy Williams
Recreate your favourite 14" and 18" Shirley costumes will complete measurement styles & targeted directions. styles contain: reprint of Thirties underthings, gown, coat and hat; well-known dotted costume, Bluebird gown, and Heidi costume. additionally integrated are illustrations of unique Shirley Temple dolls and garments taken from outdated magazines-now you could make a few of her extra recognized costumes to your dolls! a variety of b/w photographs. forty eight pages.
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6 What is the acid value of polycaprolactam (nylon-6) with average DP 500 ? ] [Ans. 7 How would you determine experimentally whether the polymerization of an unknown monomer was proceeding by a step or a chain mechanism ? 8 (a) Referring to the epoxy-amine reaction shown in Fig. 7, determine the functionality of the diglycidyl ether of bisphenol A (I) in a hardening reaction with diethylene triamine (II). (b) What is the functionality of (II) in this reaction ? [Ans. 9 Each of the following polymers can be synthesized from different monomers (a) –[–O(CH2 )5 CO–]n – (b) –(–OCH2 CH2 CH2 –)n – (c) –[–NH–(CH2 )7 –CO–]n – Show by equations the overall chemical reactions involved in the synthesis of these polymers from different monomers.
55 10 20 J molecule 1 From Eq. 524 ng nt : At low temperatures, trans states are thus preponderant. Since the backbone of polyethylene molecule is composed of a chain of tetrahedral carbon atoms, the molecule in all-trans conformation has a linear zigzag structure (like corrugated sheets) shown in (I). 5 (a) Schematic diagram showing two adjacent carbons, Cn and Cn 1 , in the main chain of polyisobutylene. (b) Newman projections of staggered conformations of adjacent carbons in the main chain. H H H C H H C H H H C C H H C C H H C C H H C H H (I) H C H H H Linear polyethylene is thus capable of close-packing into tight unit cell and is highly crystalline, despite its low cohesive energy.
The number (x) of sulfur atoms in sulfide crosslinkages is 1 or 2 in efficient vulcanization systems but may be as high as 8 under conditions where cyclic and other structures are also formed in the reaction. (c) The effect of crosslinking is to introduce points of linkage or anchor points between chain molecules, restricting their slippage. A ladder (or two-strand) structure, as shown above, is one that has an uninterrupted sequence of rings joined one to another at two connecting atoms. A semiladder structure, on the other hand, is one in which there are single bonds interconnecting some of the rings.